Field-induced slow relaxation in a monometallic manganese(III) single-molecule magnet.
نویسندگان
چکیده
High-field electron paramagnetic resonance spectroscopy shows that the structurally distorted Mn(III) ion in Na5[Mn(L-tart)2]·12H2O (1; L-tart = L-tartrate) has a significant negative axial zero-field splitting and a small rhombic anisotropy (∼1% of D). Alternating-current magnetic susceptibility measurements demonstrate that 1, which contains isolated Mn(III) centers, displays slow relaxation of its magnetization under an applied direct-current magnetic field.
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ورودعنوان ژورنال:
- Inorganic chemistry
دوره 54 1 شماره
صفحات -
تاریخ انتشار 2015